When
polymer coatings and overlays fail, over three decades of floor statistics
show that surface preparation of the concrete substrate is one of the
primary causes. The most often culprit is called laitance. It's a milky-white
to light-gray alkaline substance that consists of water, cement, and
fine aggregate particles. As the water evaporates and the substance
cures on the top of the concrete, these particles form a paste-like
consistency. Laitance occurs when water bleeds to the surface of over
wet concrete, and becomes thicker by overworking the concrete during
the compaction and finishing process. The thickness of laitance is also
influenced by the type and amount of admixtures, and the quantity of
water that is in the concrete mix or placed on top of the concrete slab
to complete the finishing process. It can very from a very thin film
up to 1/8 inch when cured.
When
laitance is cured, there is a very brittle, weak layer of cementitious
material that is poorly bonded to the concrete mass below. Simply defined,
adhesion of concrete is the state in which two surfaces are held together
by interfacial forces which consists of mechanical bonds. The bonding
mechanisms of an inorganic material such as concrete are very complex.
Cementitious materials do not bond well together, and it becomes even
more complicated when an organic polymer such as an epoxy or polyurethane
is required to adhere to inorganic material.
It
is the consensus of most major international concrete associations that
laitance must be removed before applying coatings or overlays when they
will be exposed to natural environments such as freeze-thaw or wet-dry
cycles. The same applies when protective polymer overlayment is exposed
to stresses such as impact or sheer on either exterior or interior concrete
surface.